∵DE=EB∴设∠BDE=∠ABD=x，∴∠AED=∠A=2x，∴∠BDC=∠C=∠ABC=3x，在△ABC中，3x+3x+2x=180°，解得x=22.5°．∴∠A=2x=22.5°×2=45°．故选B．
